Evaluation of Vapor Intrusion Risk from Ethylene Dibromide Using the Vertical Screening Distance Approach

Vapor intrusion (VI) occurs when volatile contaminants in the subsurface migrate through the vadose zone into overlying buildings. The 2015 U.S. EPA petroleum VI guidance recommends that additional investigation of the VI risk from gasoline hydrocarbons at the underground storage tank (UST) sites is not necessary where the vertical distance between a building and a vapor source exceeds a recommended vertical screening distance. However, due to the lack of soil-gas data on the attenuation of ethylene dibromide (EDB), additional VI investigations to evaluate VI risk from EDB are recommended at UST sites with leaded gasoline releases containing EDB. We analyzed soil-gas and groundwater concentrations of EDB from eight petroleum UST sites using a new analytical method with soil-gas detection limit <0.16 μg/m³ EDB (VI screening level at the 10⁻⁶ risk level). The analysis included (1) assessing the frequency of EDB detections ≤0.16 μg/m³ at various vertical separation distances and (2) predicting vertical screening distances for EDB using the U.S. EPA PVIScreen model for different soil types in the vadose zone above dissolved-phase and LNAPL sources. Ranges of estimated aerobic biodegradation rate constants for EDB, air exchange rates for residential buildings, and source vapor concentrations for other constituents were combined with conservative estimates of EDB source concentrations as model inputs. Concentrations of EDB in soil-gas indicated that the U.S. EPA recommended vertical screening distances are protective of VI risk from EDB. Conversely, vertical screening distances predicted by modeling were >6 ft (1.8 m) for sites with sand and loam soil above dissolved phase sources and >15 ft (4.6 m) for sites with sand soil above LNAPL sources. This predicted dependence on the vapor source type and soil type in the vadose zone highlights the importance of soil characterization for VI screening at sites with EDB sources.     

Neil Smith, 1954–2012: “The Future is Indeed Radically Open”

Investors in single-family residential properties have played a crucial role in the United States foreclosure crisis. In this paper, we analyze investor behavior in the diverse urban housing market of Fulton County, Georgia. We examine the composition of buyers of lender-owned properties at two different stages of the foreclosure crisis, and analyze the intrametropolitan geography of investment. Results indicate that large-scale investors are most active in low-value housing submarkets with high poverty and vacancy rates.     

Probabilistic assessment of wildfire hazard and municipal watershed exposure

The occurrence of wildfires within municipal watersheds can result in significant impacts to water quality and ultimately human health and safety. In this paper, we illustrate the application of geospatial analysis and burn probability modeling to assess the exposure of municipal watersheds to wildfire. Our assessment of wildfire exposure consists of two primary components: (1) wildfire hazard, which we characterize with burn probability, fireline intensity, and a composite index, and (2) geospatial intersection of watershed polygons with spatially resolved wildfire hazard metrics. This effort enhances investigation into spatial patterns of fire occurrence and behavior and enables quantitative comparisons of exposure across watersheds on the basis of a novel, integrated measure of wildfire hazard. As a case study, we consider the municipal watersheds located on the Beaverhead-Deerlodge National Forest (BDNF) in Montana, United States. We present simulation results to highlight exposure across watersheds and generally demonstrate vast differences in fire likelihood, fire behavior, and expected area burned among the analyzed municipal watersheds. We describe how this information can be incorporated into risk-based strategic fuels management planning and across the broader wildfire management spectrum. To conclude, we discuss strengths and limitations of our approach and offer potential future expansions.     

A subsurface evacuation model for submarine slope failure

Analysis of three-dimensional (3D) seismic reflection data from the Norwegian continental margin provides an insight into an unusual, buried submarine slope failure, which occurred adjacent to the later Holocene-age Storegga Slide. The identified failure, informally named the 'South Vøring Slide' (SVS), occurs in fine-grained hemipelagic and contourite sediments on a slope of 0.5°, and is characterised by a deformed seismic facies unit consisting of closely spaced pyramidal blocks and ridges bound by small normal faults striking perpendicular to the slope. The SVS contrasts with other previously described submarine slope failures in that it cannot be explained by a retrogressive model. The defining characteristic is the high relative volume loss. The area affected by sliding has thinned by some 40%, seen in combination with very modest extension in the translation direction, with line length balancing yielding an extension value of only 4.5%. The volume loss is explained by the mobilisation of an approximately 40 m thick interval at the lower part of the unit and its removal from beneath a thin overburden, which subsequently underwent extensional fragmentation. Evidence for the mobilisation of a thick fine-grained interval in the development of a submarine slope failure from a continental margin setting may have implications for the origins of other large-scale slope failures on the Norwegian margin and other glacially influenced margins worldwide.     

Architecture of the deep critical zone in the Río Icacos watershed (Luquillo Critical Zone Observatory,Puerto Rico) inferred from drilling and ground penetrating radar (GPR)

In the critical zone, surficial bedrock interactions result in the formation of a mantle of chemically‐ and physically‐altered material defined here as regolith. In the watershed of the Río Icacos, an upland river draining the Luquillo Mountains in tropical Puerto Rico, we explored the influence of lithology (quartz diorite versus hornfels‐facies volcaniclastic rock) on weathering. Regolith profiles were studied by drilling boreholes and imaging the subsurface using ground penetrating radar (GPR). Overall, the regolith structure is not laterally continuous but rather is punctuated by zones of deep fractures that host in situ weathering, corestones, and colluvial material. GPR images of these vertical zones show reflectors at 15–20 m depth. Thus, the architecture of the critical zone in the upper Luquillo Mountains is highly dependent on lithology and its influence on fracture development. At the highest elevations where hornfels overlies quartz diorite, positive feedbacks occur when the water table drops so that oxidative weathering of biotite in the more felsic rock creates microfractures and allows deeper infiltration of meteoric waters. Such exposure results in some of the fastest weathering rocks in the world and may contribute to formation of the knickpoint in the Río Icacos watershed. This work represents the first study combining GPR and drilling to look at the structure of the deep critical zone and demonstrates: (1) the importance of combining direct methods (such as drilling) with indirect methods (such as GPR) to understand the architecture of the critical zone in tropical systems; (2) the interplay of the surficial stress regime, lithology and climate in dictating the architecture of weathering. Copyright © 2016 John Wiley & Sons, Ltd.     

Radiocarbon deficiencies of US Gulf Coast lakes compromise paleo-hurricane records

Radiocarbon assays of sediments from Lake Shelby, US Gulf Coast, exhibit substantial ¹⁴C deficiencies of 9.3% and 4.7% for the limnic sapropel and associated fresh-water clams Rangia cuneata, respectively. Measured radiocarbon dates from the sapropel and clams require corrections of 785 ± 80 and 365 ± 90 ¹⁴C yr (1σ), respectively, in order to achieve consistency with the radiocarbon time scale. Lake sediments of the US Gulf Coast serve as unique repositories of pre-historic hurricane strikes. Previously unrecognized radiocarbon deficiencies likely render compromised chronologies of the paleo-hurricane records, and erroneous estimates of return period and landfall probability that are derived from the storm chronologies. The recalculated severe hurricane chronologies suggest that the annual landfall probabilities of the last millennium on the US Gulf Coast are equal to, or higher than, the preceding three millennia.     

Exploring how alternative mapping approaches influence fireshed assessment and human community exposure to wildfire

Attaining fire-adapted human communities has become a key focus of collaborative planning on landscapes across the western United States and elsewhere. The coupling of fire simulation with GIS has expanded the analytical base to support such planning efforts, particularly through the “fireshed” concept that identifies areas where wildfires could ignite and reach a human community. Previous research has identified mismatches in scale between localized community wildfire planning and the broader fireshed considering patterns of wildfire activity across landscapes. Here we expand upon this work by investigating the degree to which alternative geospatial characterizations of human communities could influence assessment of community exposure and characterization of the fireshed. We use three methods of mapping human communities (point, raster, and polygon) and develop three fireshed metrics (size, number of fires reaching houses, and number of houses exposed), and apply this analytical framework on a 2.3 million ha case study landscape encompassing the Sierra National Forest in California, USA. We simulated fire occurrence and growth using FSim for 10,000 iterations (fire seasons) at 180-m resolution. The simulation resulted in 3.9 large fires per million ha per year, with a mean size of 3432 ha. Results exhibit similarities and differences in how exposure is quantified, specifically indicating that polygons representing recognized community boundaries led to the lowest exposure levels. These results highlight how choice of the mapping approach could lead to misestimating the scope of the problem or targeting mitigation efforts in the wrong areas, and underscore the importance of clarity and spatial fidelity in geospatial data representing communities at risk.     

On the occurrence,trace element geochemistry,and crystallization history of zircon from in situ ocean lithosphere

We characterize the textural and geochemical features of ocean crustal zircon recovered from plagiogranite, evolved gabbro, and metamorphosed ultramafic host-rocks collected along present-day slow and ultraslow spreading mid-ocean ridges (MORs). The geochemistry of 267 zircon grains was measured by sensitive high-resolution ion microprobe-reverse geometry at the USGS-Stanford Ion Microprobe facility. Three types of zircon are recognized based on texture and geochemistry. Most ocean crustal zircons resemble young magmatic zircon from other crustal settings, occurring as pristine, colorless euhedral (Type 1) or subhedral to anhedral (Type 2) grains. In these grains, Hf and most trace elements vary systematically with Ti, typically becoming enriched with falling Ti-in-zircon temperature. Ti-in-zircon temperatures range from 1,040 to 660°C (corrected for a _TiO2 ≈ 0.7, a _SiO2 ≈ 1.0, pressure ≈ 2 kbar); intra-sample variation is typically ~60–150°C. Decreasing Ti correlates with enrichment in Hf to ~2 wt%, while additional Hf-enrichment occurs at relatively constant temperature. Trends between Ti and U, Y, REE, and Eu/Eu* exhibit a similar inflection, which may denote the onset of eutectic crystallization; the inflection is well-defined by zircons from plagiogranite and implies solidus temperatures of ~680–740°C. A third type of zircon is defined as being porous and colored with chaotic CL zoning, and occurs in ~25% of rock samples studied. These features, along with high measured La, Cl, S, Ca, and Fe, and low (Sm/La)_N ratios are suggestive of interaction with aqueous fluids. Non-porous, luminescent CL overgrowth rims on porous grains record uniform temperatures averaging 615 ± 26°C (2SD, n = 7), implying zircon formation below the wet-granite solidus and under water-saturated conditions. Zircon geochemistry reflects, in part, source region; elevated HREE coupled with low U concentrations allow effective discrimination of ~80% of zircon formed at modern MORs from zircon in continental crust. The geochemistry and textural observations reported here serve as an important database for comparison with detrital, xenocrystic, and metamorphosed mafic rock-hosted zircon populations to evaluate provenance.